Mechanochemical organic synthesis /
Mechanochemical Organic Synthesis is a comprehensive reference that not only synthesizes the current literature but also offers practical protocols that industrial and academic scientists can immediately put to use in their daily work. Increasing interest in green chemistry has led to the developmen...
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| Main Authors: | , |
|---|---|
| Format: | Electronic eBook |
| Language: | English |
| Published: |
Amsterdam, Netherlands :
Elsevier,
[2016]
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| Subjects: | |
| Online Access: | CONNECT |
Table of Contents:
- Front Cover; Mechanochemical Organic Synthesis; Mechanochemical Organic Synthesis; Copyright; Contents; Preface; List of Abbreviations; 1
- Practical Considerations in Mechanochemical Organic Synthesis; 1.1 A HISTORICAL PERSPECTIVE; 1.2 MODERN LABORATORY INSTRUMENTATION FOR MECHANOSYNTHESIS; 1.2.1 PLANETARY BALL MILLS; 1.2.2 MIXER (SHAKER) BALL MILLS; 1.2.3 CUSTOM-MADE BALL MILLS; 1.2.4 MILLING PARAMETERS; 1.3 CONTAMINATION FROM WEAR IN ORGANIC MECHANOSYNTHESIS; 1.4 ANALYSIS AND MONITORING OF MECHANOCHEMICAL REACTIONS; 1.4.1 ANALYTICAL METHODS IN ORGANIC SOLID-STATE CHEMISTRY
- 1.4.2 MONITORING OF MECHANOCHEMICAL REACTIONS1.4.2.1 Ex Situ Monitoring; 1.4.2.2 In Situ Monitoring; REFERENCES; 2
- Carbon-Carbon Bond- Forming Reactions; 2.1 HECK COUPLING; 2.2 SUZUKI COUPLING; 2.3 SONOGASHIRA COUPLING; 2.4 GLASER COUPLING; 2.5 MICHAEL REACTION; 2.5.1 ASYMMETRIC MICHAEL REACTION; 2.6 ALDOL CONDENSATION; 2.6.1 ASYMMETRIC ALDOL CONDENSATION; 2.7 MORITA-BAYLIS-HILLMAN REACTION; 2.8 KNOEVENAGEL CONDENSATION; 2.9 BARBIER ALLYLATION; 2.10 GEWALD REACTION; 2.11 PINACOL REACTION; 2.12 GRIGNARD AND MCMURRY REACTIONS; 2.13 GRIGNARD-ZEREWITINOFF-LIKE REACTION; 2.14 WITTIG REACTION
- 2.15 HORNER-WADSWORTH-EMMONS REACTION2.16 ASYMMETRIC ALKYLATION; 2.17 OLEFIN CROSS-METATHESIS; 2.18 CROSS-DEHYDROGENATIVE COUPLING; 2.19 REFORMATSKY REACTION; 2.20 CASCADE REACTIONS; 2.20.1 PORPHYRIN SYNTHESIS; 2.20.2 NINHYDRIN CONDENSATIONS; 2.21 ARYLAMINOMETHYLATION; 2.22 NAPHTHOPYRAN SYNTHESIS; REFERENCES; 3
- Carbon-Nitrogen Bond-Formation Reactions; 3.1 1,2-DIONE/DIAMINE CONDENSATION; 3.2 SYNTHESIS OF IMINES; 3.3 SYNTHESIS OF (THIO)SEMICARBAZONES; 3.4 SYNTHESIS OF OXIMES; 3.5 SYNTHESIS OF HYDRAZONES; 3.6 SYNTHESIS OF AZINES; 3.7 AMIDE AND THIOAMIDE BOND FORMATION
- 3.7.1 COUPLING OF ACTIVATED ACIDS AND AMINES3.7.2 ADDITION OF CUMULENES TO AMINES; 3.7.3 OXIDATIVE AMIDATION; 3.7.4 NUCLEOPHILIC ADDITION OF CARBOXYLATE; 3.7.5 CARBAMATE NITROGEN PROTECTION; 3.7.6 SYNTHESIS OF IMIDES; 3.8 SYNTHESIS OF NITRONES; 3.9 SYNTHESIS OF ENAMINES AND ENAMINE KETONES; 3.10 ALKYLATION OF NITROGEN; 3.11 SYNTHESIS OF BIGUANIDES AND GUANIDINES; 3.12 ADDITIONS TO DOUBLE AND TRIPLE BONDS; 3.12.1 AZA-MICHAEL REACTION; 3.12.2 AMINOHALOGENATION OF OLEFINS; 3.12.2.1 Aminochlorination of Olefins; 3.12.2.2 Aminobromination of Olefins; 3.12.3 INTRAMOLECULAR HYDROAMINATION
- 3.12.4 ADDITIONS TO IMINE BOND3.13 SUBSTITUTION REACTIONS; 3.14 N-ARYLATION OF AMINES; 3.15 BIGINELLI REACTION; 3.16 NITROSO BOND FORMATION/DISSOCIATION; REFERENCES; 4
- CarbondOxygen and Other Bond-Formation Reactions; 4.1 CDO BOND FORMATION REACTIONS; 4.1.1 SYNTHESIS OF ETHERS; 4.1.1.1 Glycosylation; 4.1.1.2 O-Protection; 4.1.1.3 Cyclodehydration; 4.1.1.4 Epoxides; 4.1.2 ESTERS; 4.1.2.1 Alkylation; 4.1.2.2 Decarboxylative Esterification; 4.1.2.3 Transesterification; 4.1.2.4 Anhydride Ring Opening; 4.1.2.5 Tishchenko Reaction; 4.1.2.6 Acylation; 4.2 SULFUR BOND FORMATION REACTIONS
