Pericyclic reactions : a mechanistic and problem solving approach /

Pericyclic reactions : a mechanistic and problem solving approach /

Pericyclic Reactions: A Mechanistic and Problem-Solving Approach provides complete and systematic coverage of pericyclic reactions for researchers and graduate students in organic chemistry and pharmacy programs. Drawing from their cumulative years of teaching in the area, the authors use a clear, p...

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Bibliographic Details
Main Authors: Kumar, Sunil (Author), Kumar, Vinod (Author), Singh, S. P. (Author)
Format: Electronic eBook
Language:English
Published: London, UK ; San Diego, CA, USA : Elsevier Academic Press, ©2016.
Subjects:
Pericyclic reactions.
Organic cyclic compounds.
Chemical reactions.
Online Access:CONNECT
Table of Contents:
  • Front Cover
  • Pericyclic Reactions
  • Copyright
  • To Our Families
  • Contents
  • Preface
  • Chapter 1
  • Pericyclic Reactions and Molecular Orbital Symmetry
  • 1.1 CLASSIFICATION OF PERICYCLIC REACTIONS
  • 1.2 MOLECULAR ORBITALS OF ALKENES AND CONJUGATED POLYENE SYSTEMS
  • 1.3 MOLECULAR ORBITALS OF CONJUGATED IONS OR RADICALS
  • 1.4 SYMMETRY PROPERTIES OF Ï€ OR Ï?-MOLECULAR ORBITALS
  • 1.5 ANALYSIS OF PERICYCLIC REACTIONS
  • FURTHER READING
  • Chapter 2
  • Electrocyclic Reactions
  • 2.1 CONROTATORY AND DISROTATORY MODES
  • 2.2 STEREOCHEMISTRY OF ELECTROCYCLIC REACTIONS2.3 SELECTION RULES FOR ELECTROCYCLIC REACTIONS
  • 2.4 ANALYSIS OF ELECTROCYCLIC REACTIONS
  • 2.5 ELECTROCYCLIC REACTIONS OF IONIC SPECIES
  • Chapter 3
  • Sigmatropic Rearrangements
  • 3.1 SUPRAFACIAL AND ANTARAFACIAL PROCESSES
  • 3.2 ANALYSIS OF SIGMATROPIC REARRANGEMENTS OF HYDROGEN
  • 3.3 ANALYSIS OF SIGMATROPIC REARRANGEMENTS OF ALKYL GROUP
  • 3.4 [3,3] SIGMATROPIC REARRANGEMENTS
  • 3.5 [5,5] SIGMATROPIC SHIFT
  • 3.6 [2,3] SIGMATROPIC REARRANGEMENTS
  • 3.7 PERIPATETIC CYCLOPROPANE BRIDGE: WALK REARRANGEMENTS
  • 3.8 SIGMATROPIC REARRANGEMENTS INVOLVING IONIC TRANSITION STATESChapter 4
  • Cycloaddition Reactions
  • 4.1 STEREOCHEMICAL MODES OF CYCLOADDITION
  • 4.2 FEASIBILITY OF CYCLOADDITION REACTIONS
  • 4.3 [2+2] CYCLOADDITIONS
  • 4.4 [4+2] CYCLOADDITIONS
  • 4.5 HIGHER CYCLOADDITIONS
  • 4.6 CYCLOADDITION OF MULTIPLE COMPONENTS
  • Chapter 5
  • Cheletropic Reactions and 1,3-Dipolar Cycloadditions
  • 5.1 CHELETROPIC REACTIONS
  • 5.2 1,3-DIPOLAR CYCLOADDITIONS
  • Chapter 6
  • Group Transfer, Elimination, and Related Reactions
  • 6.1 GROUP TRANSFER REACTIONS
  • 6.2 ELIMINATION REACTIONS6.3 DYOTROPIC REARRANGEMENTS
  • 6.4 ENE REACTIONS
  • 6.5 β-ELIMINATIONS INVOLVING CYCLIC TRANSITION STRUCTURES
  • Chapter 7
  • Unsolved Problems
  • Appendix
  • Solution Manual
  • Index

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