Ions in solution : basic principles of chemical interactions /
This outline of the principles and chemical interactions in inorganic solution chemistry delivers a course module in an area of considerable complexity. Problems with solutions and tutorial hints to test comprehension have been added as a feature to check readers' understanding and assist self-...
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Main Author: | |
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Format: | Electronic eBook |
Language: | English |
Published: |
Cambridge, England ; Philadelphia, Pennsylvania ; New Delhi, India :
Woodhead Publishing,
2011.
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Edition: | Second edition. |
Series: | Horwood Publishing series in chemical science.
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Subjects: | |
Online Access: | CONNECT |
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100 | 1 | |a Burgess, John. | |
245 | 1 | 0 | |a Ions in solution : |b basic principles of chemical interactions / |c John Burgess. |
250 | |a Second edition. | ||
264 | 1 | |a Cambridge, England ; |a Philadelphia, Pennsylvania ; |a New Delhi, India : |b Woodhead Publishing, |c 2011. | |
264 | 4 | |c ©1999 | |
300 | |a 1 online resource (232 pages) : |b illustrations | ||
336 | |a text |b txt |2 rdacontent | ||
337 | |a computer |b c |2 rdamedia | ||
338 | |a online resource |b cr |2 rdacarrier | ||
490 | 1 | |a Horwood Series in Chemical Science | |
504 | |a Includes bibliographical references and index. | ||
588 | 0 | |a Online resource; title from PDF title page (ebrary, viewed February 14, 2014). | |
520 | |a This outline of the principles and chemical interactions in inorganic solution chemistry delivers a course module in an area of considerable complexity. Problems with solutions and tutorial hints to test comprehension have been added as a feature to check readers' understanding and assist self-study. Exercises and projects are also provided to help readers deepen and extend their knowledge and understanding. Inorganic solution chemistry is treated thoroughlyEmphasis is placed upon NMR, UV-VIS, IR Raman spectroscopy, X-ray diffraction, and such topics as acid-base behaviour, stability constants and kinetics. | ||
505 | 0 | |a Front Cover; Ions in Solution: Basic Principles of Chemical Interactions; Copyright Page; Table of Contents; Author's preface; List ofsymbols and abbreviations; Chapter 1. Introduction; 1.1 Dissolution of salts; 1.2 Metal ions around the Periodic Table; 1.3 New aqua-metal ions; 1.4 Anions and complexes in solution; 1.5 Model for ions in solution; Chapter 2. Solvation numbers; 2.1 NMR spectroscopy; 2.2 Ion movement methods; 2.3 Review of solvation numbers; Chapter 3. Ion-solvent distances; 3.1 X-ray diffraction by solutions; 3.2 Radial distribution functions. | |
505 | 8 | |a 3.3 Results of diffraction and scattering studiesChapter 4. Ion-solvent interactions; 4.1 Ultraviolet-visible spectroscopy; 4.2 Infrared and Raman spectroscopy; 4.3 Thermochemistry of ion solvation; Chapter 5. Acid-base behaviour; hydrolysis and polymerisation; 5.1 pK values for aqua-metal ions; 5.2 Polymerisation; 5.3 Anions and ligands; 5.4 Complexes; Chapter 6. Stability constants; 6.1 Definitions; 6.2 Trends; 6.3 Chelates; 6.4 Selectivity; macrocyclic and encapsulating ligands; 6.5 Relevance; Chapter 7. Redox potentials; 7.1 Introduction and thermodynamics; 7.2 Aqua-metal ions. | |
505 | 8 | |a 7.3 Complexes7.4 Redox potentials and stability constants; Chapter 8. Kinetics and thermodynamics; Chapter 9. Kinetics and mechanisms: solvent exchange; 9.1 Introduction; 9.2 Mechanisms; 9.3 Reactivities; Chapter 10. Kinetics and mechanisms: complex formation; 10.1 Background; 10.2 The Eigen-Wilkins mechanism; 10.3 Chelate formation; 10.4 Polydentate and macrocyclic ligands; 10.5 Crown ethers and cryptands; Chapter 11. Kinetics and mechanisms: substitution at complex ions; 11.1 General; 11.2 Cobalt(III) complexes; 11.3 Platinum(II) complexes; 11.4 Pentacyanoferrates(II); 11.5 Other complexes. | |
505 | 8 | |a Chapter 12. Kinetics and mechanisms: redox reactions12.1 Introduction; 12.2 The inner-sphere mechanism; 12.3 The outer-sphere mechanism; 12.4 Intermediates, pre-equilibria, and other complications; 12.5 Metal ion oxidation of simple species; 12.6 Oxoanion oxidants; 12.7 lntramolecular electron transfer; Chapter 13. Past, present and future; Glossary; Further reading; Exercises, problems and projects; Index. | |
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