Experimental and theoretical approaches to actinide chemistry /

Experimental and theoretical approaches to actinide chemistry /

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A review of contemporary actinide research that focuses on new advances in experiment and theory, and the interplay between these two realms Experimental and Theoretical Approaches to Actinide Chemistry offers a comprehensive review of the key aspects of actinide research. Written by noted experts i...

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Bibliographic Details
Other Authors: Gibson, John K. (Editor), Jong, Wibe A. de, 1969- (Editor)
Format: Electronic eBook
Language:English
Published: Hoboken, NJ : Wiley, 2018.
Subjects:
Actinium compounds.
Actinide elements.
Heavy elements.
Actinoid Series Elements
Online Access:CONNECT
Table of Contents:
  • 1.1.Introduction / Kirk A. Peterson / Michael C. Heaven
  • 1.2.Techniques for Obtaining Actinide-Containing Molecules in the Gas Phase / Kirk A. Peterson / Michael C. Heaven
  • 1.3.Techniques for Spectroscopic Characterization of Gas-Phase Actinide Compounds / Kirk A. Peterson / Michael C. Heaven
  • 1.3.1.Conventional Absorption and Emission Spectroscopy / Kirk A. Peterson / Michael C. Heaven
  • 1.3.2.Photoelectron Spectroscopy / Kirk A. Peterson / Michael C. Heaven
  • 1.3.3.Velocity Modulation and Frequency Comb Spectroscopy / Kirk A. Peterson / Michael C. Heaven
  • 1.3.4.LIF Spectroscopy / Kirk A. Peterson / Michael C. Heaven
  • 1.3.5.Two-Photon Excitation Techniques / Kirk A. Peterson / Michael C. Heaven
  • 1.3.6.Anion Photodetachment Spectroscopy / Kirk A. Peterson / Michael C. Heaven
  • 1.3.7.Action Spectroscopy / Kirk A. Peterson / Michael C. Heaven
  • 1.3.8.Bond Energies and Reactivities from Mass Spectrometry / Kirk A. Peterson / Michael C. Heaven
  • 1.4.Considerations for Characterizing Actinide-Containing Molecules in the Gas Phase by Ab Initio Methods / Kirk A. Peterson / Michael C. Heaven
  • 1.4.1.Electron Correlation Methods / Kirk A. Peterson / Michael C. Heaven
  • 1.4.2.Relativistic Effects / Kirk A. Peterson / Michael C. Heaven
  • 1.4.3.Basis Sets / Kirk A. Peterson / Michael C. Heaven
  • 1.5.Computational Strategies for Accurate Thermodynamics of Gas-Phase Actinide Molecules / Kirk A. Peterson / Michael C. Heaven
  • 1.6.Ab Initio Molecular Spectroscopy of Gas-Phase Actinide Compounds / Kirk A. Peterson / Michael C. Heaven
  • 1.6.1.Pure Rotational and Ro-Vibrational Spectroscopy / Kirk A. Peterson / Michael C. Heaven
  • 1.6.2.Electronic Spectroscopy / Kirk A. Peterson / Michael C. Heaven
  • 1.7.Summary and Outlook / Kirk A. Peterson / Michael C. Heaven
  • Acknowledgments / Kirk A. Peterson / Michael C. Heaven
  • References / Kirk A. Peterson / Michael C. Heaven
  • 2.1.Introduction / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 2.2.Potentiometry / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 2.2.1.Potentiometric Titrations to Reveal Speciation / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 2.2.2.Overview of Potentiometry in Aqueous Actinide Chemistry / Jennifer N. Wacker / Rami J. Batrice / Karah E. Knope
  • 2.3.Optical Spectroscopy / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 2.3.1.UV-vis-NIR Spectroscopy in Actinide Speciation / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 2.3.2.Fluorescence Spectroscopy / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 2.3.3.Overview of Optical Spectroscopy in Aqueous Actinide Speciation / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 2.4.NMR Spectroscopy / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 2.4.1.Probing Chemical Equilibria by NMR / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 2.4.2.Monitoring Product Formation/Evolution by NMR Spectroscopy / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 2.4.3.Monitoring Actinide Self-Assembly by NMR Spectroscopy / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 2.4.4.Following Cluster Stability in Solution by NMR Spectroscopy / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 2.4.5.Overview of NMR Spectroscopy in Aqueous Actinide Chemistry / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 2.5.Raman Spectroscopy / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 2.5.1.Cluster Formation and Assembly / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 2.5.2.Spectral Deconvolution of Raman Data to Yield Speciation / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 2.5.3.Identifying the Nature of Cation-Cation Interactions in Solution / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 2.5.4.In the Absence of an y1: Pa(V) Speciation in HF Solutions / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 2.5.5.Computational Assignment of Vibrational Spectra / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 2.5.6.Overview of Raman Spectroscopy / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 2.6.X-ray Absorption Spectroscopy / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 2.6.1.EXAFS / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 2.6.2.Actinide Solution Speciation by EXAFS / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 2.6.3.EXAFS Structural Comparison of Complexes with Varying Oxidation States and Geometries / Karah E. Knope / Jennifer N. Wacker / Rami J. Batrice
  • 2.6.4.Overview of EXAFS / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 2.7.Small-Angle X-ray Scattering (SAXS) / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 2.7.1.Structure Elucidation by SAXS / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 2.7.2.SAXS Analysis of Cluster Evolution / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 2.7.3.Understanding Self-Assembly Processes by SAXS / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 2.7.4.Overview of SAXS / Rami J. Batrice / Jennifer N. Wacker / Karah E. Knope
  • 2.8.High-Energy X-ray Scattering (HEXS) / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 2.8.1.Determining Coordination Number and Environment about a Metal Center / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 2.8.2.Deducing Metal-Ligand Coordination Modes / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 2.8.3.Following Oligomer Formation and Stability / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 2.8.4.Overview of HEXS / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • References / Rami J. Batrice / Karah E. Knope / Jennifer N. Wacker
  • 3.1.Introduction / Thomas E. Albrecht-Schmitt / Matthew L. Marsh
  • 3.2.Fluorides / Thomas E. Albrecht-Schmitt / Matthew L. Marsh
  • 3.2.1.Trivalent and Tetravalent Fluorides / Thomas E. Albrecht-Schmitt / Matthew L. Marsh
  • 3.2.2.Pentavalent and Hexavalent Fluorides / Thomas E. Albrecht-Schmitt / Matthew L. Marsh
  • 3.2.3.Fluoride Architectures / Thomas E. Albrecht-Schmitt / Matthew L. Marsh
  • 3.3.Borates / Thomas E. Albrecht-Schmitt / Matthew L. Marsh
  • 3.3.1.Functionalized Borates / Thomas E. Albrecht-Schmitt / Matthew L. Marsh
  • 3.3.2.Transuranic Borates / Thomas E. Albrecht-Schmitt / Matthew L. Marsh
  • 3.4.Sulfates / Thomas E. Albrecht-Schmitt / Matthew L. Marsh
  • 3.4.1.Thorium and Uranium / Thomas E. Albrecht-Schmitt / Matthew L. Marsh
  • 3.4.2.Transuranic Frameworks / Thomas E. Albrecht-Schmitt / Matthew L. Marsh
  • 3.5.Phosphates / Thomas E. Albrecht-Schmitt / Matthew L. Marsh
  • 3.6.Conclusion / Thomas E. Albrecht-Schmitt / Matthew L. Marsh
  • References / Matthew L. Marsh / Thomas E. Albrecht-Schmitt
  • 4.1.Introduction / Nikolas Kaltsoyannis / Trevor W. Hayton
  • 4.2.Overview of Actinide Organometallic Chemistry / Nikolas Kaltsoyannis / Trevor W. Hayton
  • 4.2.1.Overview of Thorium Organometallics / Nikolas Kaltsoyannis / Trevor W. Hayton
  • 4.2.2.Overview of Uranium Organometallics / Nikolas Kaltsoyannis / Trevor W. Hayton
  • 4.2.3.Overview of Transuranium Organometallics / Nikolas Kaltsoyannis / Trevor W. Hayton
  • 4.3.Overview of Theoretical Methods / Nikolas Kaltsoyannis / Trevor W. Hayton
  • 4.4.New Theoretical and Experimental Tools for Evaluating Covalency in the 5f Series / Nikolas Kaltsoyannis / Trevor W. Hayton
  • 4.4.1.The Quantum Theory of Atoms-in-Molecules / Nikolas Kaltsoyannis / Trevor W. Hayton
  • 4.4.2.Ligand K-edge X-ray Absorption Spectroscopy / Nikolas Kaltsoyannis / Trevor W. Hayton
  • 4.4.3.Optical Spectroscopy / Nikolas Kaltsoyannis / Trevor W. Hayton
  • 4.4.4.Nuclear Magnetic Resonance (NMR) Spectroscopy / Nikolas Kaltsoyannis / Trevor W. Hayton
  • 4.4.5.Electrochemistry / Nikolas Kaltsoyannis / Trevor W. Hayton
  • 4.5.Notable Discoveries in Actinide-Carbon Chemistry / Nikolas Kaltsoyannis / Trevor W. Hayton
  • 4.5.1.An(II) Complexes / Nikolas Kaltsoyannis / Trevor W. Hayton
  • 4.5.2.Pi-Acceptor Ligand Complexes / Nikolas Kaltsoyannis / Trevor W. Hayton
  • 4.5.3.(Inverted) Arene Sandwich Complexes / Nikolas Kaltsoyannis / Trevor W. Hayton
  • 4.5.4.Phosphorano-Stabilized Carbene Complexes / Nikolas Kaltsoyannis / Trevor W. Hayton
  • 4.5.5.Homoleptic Alkyl and Aryl Complexes / Nikolas Kaltsoyannis / Trevor W. Hayton
  • 4.6.Single and Multiple Bonding between Uranium and Group 15 Elements / Nikolas Kaltsoyannis / Trevor W.
  • Hayton
  • 4.7.Complexes with Group 16 Donor Ligands / Nikolas Kaltsoyannis / Trevor W. Hayton
  • 4.7.1.Terminal Mono-oxo Complexes / Nikolas Kaltsoyannis / Trevor W. Hayton
  • 4.7.2.Complexes with Heavy Chalcogen (S, Se, Te) Donors / Nikolas Kaltsoyannis / Trevor W. Hayton
  • 4.8.ACtinyl and Its Derivatives / Trevor W. Hayton / Nikolas Kaltsoyannis
  • 4.8.1.Inverse Trans Influence (ITI) / Trevor W. Hayton / Nikolas Kaltsoyannis
  • 4.8.2.Imido-Substituted Analogues of Uranyl / Trevor W. Hayton / Nikolas Kaltsoyannis
  • 4.8.3.Progress Toward the Isolation of a cis-Uranyl Complex / Nikolas Kaltsoyannis / Trevor W. Hayton
  • 4.9.Organoactinide Single-Molecule Magnets / Trevor W. Hayton / Nikolas Kaltsoyannis
  • 4.10.Future Work / Nikolas Kaltsoyannis / Trevor W. Hayton
  • Acknowledgments / Trevor W. Hayton / Nikolas Kaltsoyannis
  • References / Trevor W. Hayton / Nikolas Kaltsoyannis
  • 5.1.Introduction / Aurora E. Clark / Ping Yang / Jenifer C. Shafer
  • 5.2.Overview of Separations Processes / Aurora E. Clark / Ping Yang / Jenifer C. Shafer
  • 5.2.1.Classic Processes-U/Pu Recovery / Ping Yang / Aurora E. Clark / Jenifer C. Shafer
  • 5.2.2.Advanced Separation Processes-Am/Cm Recovery / Aurora E. Clark / Ping Yang / Jenifer C. Shafer
  • 5.2.3.Aqueous-Based Complexants for Trivalent An/Ln Separation / Ping Yang / Aurora E. Clark / Jenifer C. Shafer
  • 5.2.4.Recent Trends in Aqueous-Based Trivalent An/Ln Separations / Aurora E. Clark / Ping Yang / Jenifer C. Shafer

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